Journal of Fluorine Chemistry p. 191 - 198 (1982)
Update date:2022-08-11
Topics:
Posner, Gary H.
Ellis, Jerry W.
Ponton, John
We have discovered that Woelm chromatographic γ-alumina substantially accelerates hydrolysis (and methanolysis) of acyl and phosphoryl fluorides.Compared to the corresponding homogeneous reactions, these heterogeneous alumina-promoted reactions occur about 250-350 times faster for acyl fluorides and about 1800-3000 times faster for phosphoryl fluorides.
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