Ring opening reaction of epoxides with diphenyl phosphorazidate

DOI: 10.1016/S0040-4039(99)01440-9

Source and publish data:

Tetrahedron Letters p. 7105 - 7108 (1999)

Update date:2022-08-11

Topics:

Authors:

Mizuno, Masanori

Shioiri, Takayuki

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Article abstract of DOI:10.1016/S0040-4039(99)01440-9

Diphenyl phosphorazidate with 4-dimethylaminopyridine and lithium perchlorate opens epoxides regio- and stereoselectively to give O- diphenylphosphoryl vicinal azidohydrins: For the α,β-epoxy ketones and esters, only the corresponding α-azidovinyl ketones

Full text of DOI:10.1016/S0040-4039(99)01440-9

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