Tetrahedron Letters p. 3211 - 3214 (1982)
Update date:2022-08-10
Topics:
Fukushima, Motoo
Jones, Maitland
Brinker, Udo H.
When 1,1-diiodoneopentane is passed through a hot tube containing methyllithium-coated Pyrex chips, 1,1-dimethylcyclopropane and 2-methyl-2-butene are produced in near quantitative yield.The ratio of products indicates that the intermediate carbene is the same as is produced from thermal or photosensitized decomposition of tert-butyldiazomethane but different from that formed by direct irradiation of the diazo compound.
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Doi:10.1007/BF01177025
(1995)Doi:10.1021/ja00294a074
(1985)Doi:10.1002/cctc.201500673
(2015)Doi:10.1007/BF00474487
(1992)Doi:10.14233/ajchem.2019.21795
(2019)Doi:10.1007/BF00854441
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