Synthesis of AB Ring Model System of Taxol via Allylation of 8-Membered Ring Compound and Intramolecular Aldol Condensation

DOI: 10.1246/cl.1995.229

Source and publish data:

Chemistry Letters p. 229 - 230 (1995)

Update date:2022-08-10

Topics:

Authors:

Mukaiyama, Teruaki

Shiina, Isamu

Kimura, Kaname

Akiyama, Yuji

Iwadare, Hayato

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Article abstract of DOI:10.1246/cl.1995.229

1-t-Butyldimethylsiloxy-8,11,11-trimethylbicyclo<5.3.1>undec-7-en-9-one (2) has been synthesized via intramolecular aldol condensation of the precursor 3 by combined use of lithium diisopropylamide (LDA) and CeCl3. the dicarbonyl compound 3 was prepared b

Full text of DOI:10.1246/cl.1995.229

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