Electronic and molecular structure of room-temperature stable triplet carbene as studied by ESR spectroscopy

Article abstract of DOI:10.1080/10587259608033685

A ground-state triplet diphenylcarbene derivative, 2,2′,4,4′,6,6′-hexabromodiphenylcarbene 1 was synthesized and generated to be a model for chemically stable organic high-spin molecules. Electron Spin Resonance spectroscopy showed that 1 was a triplet mo

Full text of DOI:10.1080/10587259608033685

This article was downloaded by: [Tulane University]
On: 04 January 2015, At: 03:56
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number: 1072954 Registered
office: Mortimer House, 37-41 Mortimer Street, London W1T 3JH, UK
Molecular Crystals and Liquid Crystals
Science and Technology. Section A.
Molecular Crystals and Liquid Crystals
Publication details, including instructions for authors and
subscription information:
http://www.tandfonline.com/loi/gmcl19
Electronic and Molecular Structure
of Room-Temperature Stable
Triplet Carbene as Studied by ESR
Spectroscopy
a
b
c
Katsuhiko Furukawa , Takeji Takui , Koichi Itoh , Tetsuya
d
d
d
Watanabe , Katsuyuki Hirai & Hideo Tomioka
a
Advanced Science and Technology Center for Cooperative
Research , Kyushu University , 6-1 Kasugakoen, Kasuga,
Fukuoka, 816, Japan
b
Department of Chemistry, Faculty of Science , Osaka City
University , 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka, 558, Japan
c
Department of Material Science, Faculty of Science , Osaka
City University , 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka, 558,
Japan
d
Chemistry Department for Materials, Faculty of Engineering ,
Mie University , Uehama, Tsu, Mie, 514, Japan
Published online: 24 Sep 2006.
To cite this article: Katsuhiko Furukawa , Takeji Takui , Koichi Itoh , Tetsuya Watanabe ,
Katsuyuki Hirai & Hideo Tomioka (1996) Electronic and Molecular Structure of Room-Temperature
Stable Triplet Carbene as Studied by ESR Spectroscopy, Molecular Crystals and Liquid Crystals
Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 278:1, 271-278, DOI:
10.1080/10587259608033685
To link to this article: http://dx.doi.org/10.1080/10587259608033685
PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all the information (the
“
Content”) contained in the publications on our platform. However, Taylor & Francis,
our agents, and our licensors make no representations or warranties whatsoever as to
the accuracy, completeness, or suitability for any purpose of the Content. Any opinions
and views expressed in this publication are the opinions and views of the authors,

and are not the views of or endorsed by Taylor & Francis. The accuracy of the Content
should not be relied upon and should be independently verified with primary sources
of information. Taylor and Francis shall not be liable for any losses, actions, claims,
proceedings, demands, costs, expenses, damages, and other liabilities whatsoever
or howsoever caused arising directly or indirectly in connection with, in relation to or
arising out of the use of the Content.
This article may be used for research, teaching, and private study purposes. Any
substantial or systematic reproduction, redistribution, reselling, loan, sub-licensing,
systematic supply, or distribution in any form to anyone is expressly forbidden. Terms
&
Conditions of access and use can be found at http://www.tandfonline.com/page/
terms-and-conditions