Helvetica Chimica Acta p. 1879 - 1885 (1987)
Update date:2022-08-29
Topics:
Snowden, Roger L.
Linder, Simon M.
Muller, Bernard L.
Schulte, Karl H.
Starting from γ- and δ-lactones 1-3, a two-step preparation of 3-hydroxypropyl and 4-hydroxybutyl propenyl ketones 10-18 is described, involving as the key step the β-cleavage of the bis(homoallylic) potassium alkoxides 4a-9a.This novel methodology is illustrated by a short synthesis of (+/-)-rose oxide (20).
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Doi:10.1039/c4cc07620f
(2014)Doi:10.1016/j.molcatb.2014.04.004
(2014)Doi:10.1007/BF00949701
(1981)Doi:10.1021/ja01556a008
()Doi:10.1021/acs.organomet.8b00209
(2018)Doi:10.1359/jbmr.2001.16.5.823
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