Tetrahedron Letters p. 5683 - 5686 (1991)
Update date:2022-08-28
Topics:
Chong, J. Michael
Mar, Eduardo K.
The porcine pancreatic lipase (PPL) catalyzed esterifications of α-hydroxystannanes RCH(OH)SnMe3 (R = Me, Et) and MeCH(OH)SnEt3 with 2,2,2-trifluoroethyl valerate afford good yields and excellent enantiomeric (>95 percent ee) purities of the (S)-valerate and the (R)-α-hydroxystannane.Key Words: α-alkoxystannanes; enantiomerically enriched; enzymatic esterification; porcine pancreatic lipase.
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