Synthesis and Conformational Analysis of cis,cis-1,3,5-Trimethylcyclohexane-1,3,5-tricarboxylic Acid

DOI: 10.1021/jo00338a014

Source and publish data:

Journal of Organic Chemistry p. 5140 - 5143 (1981)

Update date:2022-08-11

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Authors:

Kemp, D. S.

Petrakis, Konstantinos S.

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Article abstract of DOI:10.1021/jo00338a014

Conversion of 3,5,7-trimethyladamantan-1-ol to a hypobromite, fragmentation in situ, and oxidation with KMnO4 generate the lactone, 6, of cis,cis-1,3,5-trimethyl-1-(hydroxymethyl)cyclohexane-3,5-dicarboxylic acid, which can in turn be oxidized by RuO4-HIO

Full text of DOI:10.1021/jo00338a014

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