Journal of the Chemical Society. Chemical communications p. 528 - 530 (1986)
Update date:2022-08-10
Topics:
Latham, John A.
Branchaud, Bruce P.
Chen, Y.-C. Jack
Walsh, Christopher
Enzymic oxidation of propargylic and allylic selenides has been carried out and the resulting selenoxides found to readily undergo 2,3-sigmatropic rearrangement; the propargylic product undergoes fragmentation while the allylic product yields racemic alcohols.
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