Tetrahedron Letters p. 1521 - 1524 (1984)
Update date:2022-08-11
Topics:
Arys, Maria
Christensen, Torben B.
Eriksen, Jens
Besides known reduction and solvent addition products, the photolysis of 1,3-dimethyluracil in methanol resulted in formation of the enamine 2-methoxycarbonyl-N-methyl-3-methylaminopropenamide (5) via a novel ring-opening reaction.A mechanism for the formation of 5 is suggested and its structure was confirmed by an independent synthesis.
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