Bicycloocta-1,3,5-triene: 2-Mono- and 2,5-Disubstituted Derivatives via Highly Regioselective Lithiation of Its Cr(CO)3 Complex and via Reductive Silylation / Oxidation

DOI: 10.1002/hlca.19900730720

Source and publish data:

Helvetica Chimica Acta p. 1970 - 1979 (1990)

Update date:2022-08-11

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Authors:

Kuendig, E. Peter

Perret, Celia

Rudolph, Bruno

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Article abstract of DOI:10.1002/hlca.19900730720

Treatment of <η⁶-(bicyclo<4.2.0>octa-1,3,5-triene)>tricarbonylchromium(0) (2) with BuLi or lithium 2,2,6,6-tetramethylpiperidinide (TMPLi) gives rise to a highly regioselective deprotonation at C(2).Subsequent reaction with electrophiles (6 exa

Full text of DOI:10.1002/hlca.19900730720

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