An Asymmetric Nitroolefination of α-Alkyl-γ-and δ-Lactones with Modified Nitroenamines

DOI: 10.1016/0040-4020(95)00683-Y

Source and publish data:

Tetrahedron p. 10857 - 10866 (1995)

Update date:2022-08-03

Topics:

Authors:

Nishide, Kiyoharu

Kurosaki, Ryuichi

Hosomi, Kouichi

Imazato, Hitoshi

Inoue, Takehisa

et al. et al.

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Article abstract of DOI:10.1016/0040-4020(95)00683-Y

New chiral nitroenamines 4a,b having (S)-2-t-butyldimethylsiloxymethylpyrrolidine as an auxiliary were found to be very effective for asymmetric nitroolefination of α-alkyl-γ- and δ-lactones.The enantiomeric excess of the product increased remarkably in t

Full text of DOI:10.1016/0040-4020(95)00683-Y

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