COMPLETE RETENTION OF CHIRALITY IN THE PALLADIUM CATALYZED CYCLIZATION OF METHYL (R)-3-OXO-7-METHOXYCARBONYLOXY)-8-NONENOATE

DOI: 10.1246/cl.1984.1657

Source and publish data:

Chemistry Letters p. 1657 - 1660 (1984)

Update date:2022-08-29

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Authors:

Yamamoto, Keiji

Deguchi, Ryoji

Ogimura, Yoshinobu

Tsuji, Jiro

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Article abstract of DOI:10.1246/cl.1984.1657

Optically active methyl (R)-3-oxo-7-methoxycarbonyloxy)-8-nonenoate (1) underwent intramolecular allylation catalyzed by Pd(OAc)2-dppe in THF at room temperature to give racemic 3-vinyl-2-methoxy-carbonylcyclohexanone (3), whereas similar palladium-cataly

Full text of DOI:10.1246/cl.1984.1657

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