Photoinduced Direct Synthesis of Silylene-Bridged Dinuclear Iron Complexes5-C5H5)2Fe2(CO)2(μ-CO)(μ-SiHR)> from 5-C5H5)Fe(CO)2SiMe3> and RSiH3 (R=t-Bu, (CMe2)2H)

DOI: 10.1246/cl.1987.2247

Source and publish data:

Chemistry Letters p. 2247 - 2250 (1987)

Update date:2022-08-10

Topics:

Authors:

Tobita, Hiromi

Kawano, Yasuro

Shimoi, Mamoru

Ogino, Hiroshi

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Article abstract of DOI:10.1246/cl.1987.2247

Photolysis of (Cp=η⁵-C5H5) in the presence of RSiH3 (R=t-Bu, (CMe2)2H) afforded silylene-bridged dinuclear complexes .The structure of the complex was determined by X-ra

Full text of DOI:10.1246/cl.1987.2247

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