Stereo and regioselective synthesis of (Z)-β-arylseleno-α,β- unsaturated ketones via selenocarbonylation addition of arylselenoesters to alkynes catalyzed by copper(I)

DOI: 10.1016/S0040-4039(98)00086-0

Source and publish data:

Tetrahedron Letters p. 1933 - 1936 (1998)

Update date:2022-08-12

Topics:

Authors:

Zhao, Chang-Qiu

Huang, Xian

Meng, Ji-Ben

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Article abstract of DOI:10.1016/S0040-4039(98)00086-0

Selenocarbonylation addition reaction of selenoesters to nonactived terminal alkynes under the catalysis of CuX products (Z)- β-arylseleno-α,β-unsaturated ketones in high selectivity and high yields. The mechanism of this reaction is also discussed.

Full text of DOI:10.1016/S0040-4039(98)00086-0

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