Angewandte Chemie - International Edition in English p. 774 - 776 (1997)
Update date:2022-08-17
Topics:
Evans
Forrestal
Ziller
Polymerization of ethylene is initiated by [Sm(C5Me5)3], an observation that led to a new synthetic route to this Sm(III) compound. Tetramethylfulvalene proved to be the crucial reagent and was also used in the synthesis of [U(C5Me5)3], the first tris(pentamethylcyclopentadienyl) complex of an actinide metal (see structure on right).
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