Stereocontrolled synthesis of the BC ring system of Taxol

DOI: 10.1246/cl.1997.1139

Source and publish data:

Chemistry Letters p. 1139 - 1140 (1997)

Update date:2022-08-28

Topics:

Authors:

Shiina, Isamu

Iwadare, Hayato

Sakoh, Hiroki

Tani, Yu-Ichirou

Hasegawa, Masatoshi

Saitoh, Katsuyuki

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1997.1139

Optically active 2α,10β-dibenzyloxy-11β-(t-butyldimethylsiloxy)-7β-hydroxy- 1α-(4-methoxybenzyloxy)-8β,15,15-trimethyl-4-methylene-trans- bicyclo[6.4.0]dodecan-9-one 2 that corresponds to BC ring system of Taxol was prepared from 8-membered ring enone 3 i

Full text of DOI:10.1246/cl.1997.1139

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Product name:2α,10β-dibenzyloxy-11β-(t-butyldimethylsiloxy)-7β-hydroxy-1α-(p-methoxybenzyloxy)-8β,15,15-trimethyl-4-methylene-trans-bicyclo[6.4.0]dodecan-9-one

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