Tetrahedron Letters p. 1643 - 1646 (1985)
Update date:2022-08-11
Topics:
Hoffmann, Reinhard W.
Froech, Sybille
Addition of the enol borates 2 to aldehydes generated the internally protected aldols 3.These were subjected in situ to an allyl metal addition giving the 1,3-diols 7 or 13.This constitutes a rapid evolution of a carbon skeleton by a highly correlated tandem aldol-addition / allyl metal addition.
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