Journal of Fluorine Chemistry p. 75 - 86 (1981)
Update date:2022-08-16
Topics:
Burdon, J.
Childs, A.
Parsons, I. W.
Rimmington, T. W.
Pyrolysis of polyfluorocyclohexadienes at 475-480 deg C over new quartz or Pyrex glass gave products derived from 1,5-sigmatropic migrations of fluorine; 1,3-migrations occurred to only a small degree.As the quartz or glass aged, other processes - 1,3-migrations and defluorinations to aromatics - began to occur; these appear to be due in some way to fluoride ion, since pyrolysis over sodium fluoride gave similar products.
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