Generation of a thiazole o-quinodimethane from an imino derivative and its intermolecular Diels-Alder trapping with alkynes or quinones

DOI: 10.1248/cpb.47.1064

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Chemical and Pharmaceutical Bulletin p. 1064 - 1067 (1999)

Update date:2022-08-11

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Authors:

Jouve, Karine

Pautet, Felix

Domard, Monique

Fillion, Houda

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Article abstract of DOI:10.1248/cpb.47.1064

(E)-5-(N-Benzylformimidoyl)-4-methylthiazole 3 was prepared in good yield from 5-formyl-4-methylthiazole and benzylamine. Treatment of 3 with methylchloroformate in the presence of ethyldiisopropylamine in refluxing toluene has generated o-quinodimethane

Full text of DOI:10.1248/cpb.47.1064

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