Organic Letters p. 1940 - 1944 (2021)
Update date:2022-08-10
Topics:
Takeda, Daiki
Yoritate, Makoto
Yasutomi, Hiroki
Chiba, Suzuka
Moriyama, Takahiro
Yokoo, Atsushi
Usui, Kazuteru
Hirai, Go
C-Glycosides are metabolically stable mimics of natural O-glycosides and are expected to be useful tools for investigation of the biological functions of glycans. Here, we describe the synthesis of a series of aryl and vinyl C-glycosides by stereoinvertive sp3-sp2 cross-coupling reactions of 2-deoxyglycosyl boronic acid derivatives with aryl or vinyl halide, mediated by a photoredox/nickel dual catalytic system. Hydrogenation of the vinyl C-glycosides afforded C-linked 2′-deoxydisaccharide analogues.
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Doi:10.1002/chem.200400075
(2004)Doi:10.1021/ja028448i
(2003)Doi:10.1021/op034083q
(2003)Doi:10.1063/1.456707
(1989)Doi:10.1016/j.tetlet.2006.08.005
(2006)Doi:10.1016/S0040-4039(00)93424-5
(1991)
