Tetrahedron Letters p. 5963 - 5966 (1986)
Update date:2022-08-17
Topics:
Rossi, Rita H. de
Veglia, Alicia V.
The product distribution in the iodination of phenol with I2 in water solution is buffer and pH dependent with the ortho product increasing at low pH and low buffer concentration.This effect is attributed to different rates of proton transfer form the 4-iodo-2,5-; and 2-iodo-3,5-cyclohexadienone intermediate.
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