Tetrahedron p. 3991 - 3994 (1983)
Update date:2022-08-30
Topics:
Ravindranath, B.
Srinivas, P.
The title reaction yielded trans-carvyl chloride 2 and pinol 3.The formation of pinol and the specific rotation of the carvyl chloride are affected by the presence of acid.The implications of these findings on the understanding of the course of he reaction are discussed.Use of an acid scavenger is recommended in application of the PPh3-CCl4 reagent for acid sensitive compounds.A bimolecular, concerted group transfer mechanism (Scheme 2) is suggested for the decomposition of the intermediate alkoxytriphenylphosphonium halide 7.
View More
website:http://www.sigmaaldrich.com
Contact:800 558-9160
Address:Industriestrasse 25CH-9471 Buchs SGSwitzerland
Contact:+86-27-85733560
Address:NO.308,QINGNIAN RD.,WUHAN,CHINA
Contact:732.938.2777
Address:5012 Industrial Road Farmingdale, NJ 07727
Hubei ShiNan Pharmaceutical Chemical co., Ltd.(expird)
Contact:+86-13554447107
Address:Wuhan HongShanOu wu no road 378 future residence building 1 unit 14 layer no. 1401 A
Shandong united-rising pharmaceutical cooperation.,ltd.
Contact:008653187965009
Address:171No., Jing5 Road, Shizhong District, Jinan, China
Doi:10.1016/S0040-4039(01)84537-8
(1972)Doi:10.1021/ja00426a044
(1976)Doi:10.1021/jacs.9b11056
(2020)Doi:10.1021/ja00990a059
(1967)Doi:10.1021/jo01034a029
(1964)Doi:10.1016/S0040-4020(97)00741-2
(1997)
