Journal of Organic Chemistry p. 3943 - 3949 (1984)
Update date:2022-08-17
Topics:
Lipshutz, Bruce H.
Kozlowski, Joseph A.
Wilhelm, Robert S.
The nature of organocuprates of general formula R2Cu(CN)Li2, derived from CuCN and 2RLi, is described in terms of their structural integrity in solution.A combination of chemical and spectroscopic tests conclusively demonstrates facile dissociation-reassociation of alkyl groups on copper.Data derived from both IR and variable temperature NMR spectra suggest that different aggregation states between Et2O and THF based solutions of these reagents exist.
View More
Shijiazhuang Haotian Chemical Co., Ltd.
Contact:86-311-85044374
Address:293 Donggang Road
website:http://www.sagechem.com
Contact:+86-571-86818502
Address:Room C1301, New Youth Plaza, 8 Jia Shan Road, Hangzhou, China
Jiaxing Trustworthy Import And Export Co.,Ltd
Contact:+86-573-82030555
Address:Room 1202, Unit B, Charming plaza,No.1558 East Zhongshan Road , Jiaxing City, Zhejiang Province, China.
Jiangxi Hito Chemical Co., Ltd.
Contact:+86-792-3170318
Address:No. 6, Tianhong Ave., Xinghuo Industry Park, Yongxiu, Jiujiang, Jiangxi, China
Contact:86-28-61993785
Address:No.70-13-21, North Section, Erhuan
Doi:10.1016/j.bioorg.2021.104805
(2021)Doi:10.1016/0040-4039(96)00386-3
(1996)Doi:10.1021/acs.orglett.5b03415
(2016)Doi:10.1039/a708124c
(1998)Doi:10.1021/jo500807d
(2014)Doi:10.1016/S0040-4039(00)95179-7
(1989)
