Tetrahedron Letters p. 5649 - 5652 (1984)
Update date:2022-08-29
Topics:
Stephan, D.
Gorgues, A.
le Coq, A.
α,α'-Dibromoorthoxylenes undergo a very fast reductive elimination on treatment with chromous chloride, affording the reactive intermediate orthoquinodimethanes which evolve into spiroorthoxlylenes 2 or may be trapped with dienophiles (adducts 3 and 4).Some attempts in the field of anthracycline precursors are reported.
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