Organometallics p. 4289 - 4290 (1993)
Update date:2022-08-11
Topics:
Veneziani, Guilaine
Réau, Régis
Bertrand, Guy
Thermolysis of bis(trimethylstannyl)diazomethane (1) or bis(tributylstannyl)diazomethane (2) affords the corresponding bis(stannyl)carbodiimides 3-4. Bis(trimethylstannyl)carbodiimide (3) is also obtained at room temperature by palladium-catalyzed isomerization of diazo derivative 1 and is a powerful precursor of elaborated carbodiimides.
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