Palladium-Catalyzed Cyclization of Benzyl Halides and Related Electrophiles Containing Alkenes and Alkynes as a Novel Route to Carbocycles

DOI: 10.1021/jo00272a006

Source and publish data:

Journal of Organic Chemistry p. 2507 - 2508 (1989)

Update date:2022-08-29

Topics:

Authors:

Wu, Guang-zhong

Lamaty, Frederic

Negishi, Ei-ichi

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Article abstract of DOI:10.1021/jo00272a006

Treatment of benzyl halides and related electrophiles containing alkene and alkyne groups with a catalytic amount of Pd complexes, such as Pd(PPh3)4, provides the corresponding cyclization products containing five- through seven-membered rings often with retention of the alkene regiochemistry.

Full text of DOI:10.1021/jo00272a006

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