Tetrahedron Letters p. 8017 - 8020 (1997)
Update date:2022-08-29
Topics:
Faust, Ruediger
Goebelt, Bernd
A general procedure for a palladium-mediated organyl group transfer from organostannanes to bis(imidoyl chlorides) has been developed on the basis of the Pd2(dba)3·CHCl3 / AsPh3 catalyst system. This protocol allows the synthesis of 2,3-dialkynyl-1 ,4-diazabutadienes and of trialkynyl-1,3,5-triazines from cyanuric chloride.
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Doi:10.1021/acs.joc.8b01204
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