
Tetrahedron Letters p. 311 - 314 (1999)
Update date:2022-08-11
Topics:
Honzawa
Mizutani
Shibasaki
Treatment of (±)-4 with Pd(OAc)2, DPPP, TBAB and K2CO3 in toluene gave 16β in a highly stereoselective manner (17:1, 90%). Moreover, reaction of(±)-4 with Pd(OAc)2, (R)-Tol-BINAP and K2CO3 in toluene afforded 16β in 96% ee and in 20% yield.
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