Journal of Organometallic Chemistry p. 1 - 8 (1980)
Update date:2022-08-29
Topics:
Busse, P. J.
Hrung, C-P.
Irgolic, K. J.
O'Brien, D. H.
Kolar, F. L.
Seoud, Omar A. El
Diphenyllithioarsine reacts with aldehydes (RCHO, R=CH2CH3, CH(CH3)2, and Ph) to form lithium salts of α-hydroxyalkylarsines.Protonation of the lithium salts gives α-hydroxyalkylarsines.Diphenylarsine reacts with aldehydes below room temperature in the absence of solvents to produce white solids.The reactions are rapid in the presence of acid catalysts.Proton and carbon-13 NMR, infrared and Raman spectra show that the products are diphenyl-(α-hydroxyalkyl)arsines, Ph2AsCHOHR.These compounds are thermally unstable.In organic solvents, equilibrium is established between the α-hydroxyalkylarsines and the aldehyde and diphenylarsine.
View More
Xi'an HO-SHINE Bio-Technology Co., Ltd
Contact:+86 (29) 8248-5435/18292020086
Address:No.6 Shiyuan Road Xian City Shaanxi Province, 710048 China
Jiangsu Hualun Chemical Industry Co., Ltd
website:http://www.hualunchem.com
Contact:+86-0514-86464168 86507985
Address:39# Middle Renmin Road, Dinghuo Town
Contact:+86-21-56338808
Address:799 Dunhuang Road, Putuo
Allright GC (Jinan) Biotechnology Ltd.
website:https://www.argcbiotech.com/
Contact:86-18405413579-
Address: No.27566 of Jingshiroad, Huaiyin District, Jinan City(250011), Shandong Province, China.
Beijing Zhongshuo Pharmaceutical T & D Co.,Ltd
Contact:0086-10-64430626
Address:ea No 16, HEPINGLI,DONGCHENG DISTRICT,BEIJING,P.R.CHINA.
Doi:10.1021/ja9828713
(1999)Doi:10.1016/j.mcat.2020.110945
(2020)Doi:10.1002/pssa.200723162
(2008)Doi:10.1016/j.tetlet.2007.02.055
(2007)Doi:10.1016/j.bmcl.2009.09.114
(2009)Doi:10.1021/jm800741n
(2008)
