Tetrahedron Letters p. 6975 - 6978 (1999)
Update date:2022-08-12
Topics:
Lee, Phil Ho
Cho, Minkyoung
Han, In-Sup
Kim, Sunggak
Phosphoniosilylation of a,β-enones with TBSOTf and triphenylphosphine at 0 °C affords 3-tert-butyldimethylsilyloxyalk-2-enylphosphonium salts, which undergo facile nucleophilic substitution with various nucleophiles to give 3-substituted silyl enol ethers
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