Journal of the Chemical Society - Faraday Transactions p. 1041 - 1048 (1993)
Update date:2022-08-11
Topics:
Al-Alousy, Ahmad
Alshehri, Saad
Blandamer, Michael J.
Blundell, Nicholas J.
Burgess, John
et al.
Kinetics of the base hydrolysis of several iron(II)-diimine complexes, including two with terdentate ligands and one with an encapsulating ligand, and of the peroxodisulfate oxidation of three ternary iron(II)-diimine-cyanide complexes, are reported for reaction in dimethyl sulfoxide (DMSO)-water mixtures at 298.15 K.Solubilities of simple and complex salts have been determined in these mixtures, both to extend the range of simple and complex ion-transfer chemical potentials and to provide the basis for initial-state/transition-state analyses of reactivity trends for several of the base hydrolysis and peroxodisulfate oxidations.Cases are identified where the destabilisation of hydroxide ions, OH(-)(aq), by added DMSO increases the rate of base hydrolysis.We also identify cases where compensation effects result in only a small change in rate constant for oxidation by peroxodisulfate where DMSO is added.
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