C-H Bond activation of alkenecarboxylates by ruthenium complexes having triphenylphosphine ligands

DOI: 10.1016/0022-328X(93)83416-S

Source and publish data:

Journal of Organometallic Chemistry p. 179 - 186 (1993)

Update date:2022-08-16

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Authors:

Komiya, Sanshiro

Aoki, Yuichi

Mizuho, Yuji

Oyasato, Naohiko

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Article abstract of DOI:10.1016/0022-328X(93)83416-S

Reactions of alkenecarboxylates with (1) or RuH2(PPh3)4 (2) give hydrido(1-alkoxycarbonyl-η³-allyl-C¹, C³)ruthenium(II) complexes, RuH(η³-CH(R)CHCHCOOR')(PPh3)2 (R = H, R' = Me (3a), Et (3b), n-Bu (3c)

Full text of DOI:10.1016/0022-328X(93)83416-S

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Product name:{Ru(hydrogen)2(nitrogen)(triphenylphosphine)3}

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