Chemistry Letters p. 1033 - 1036 (1985)
Update date:2022-08-11
Topics:
Shinkai, Seiji
Koreishi, Hiroshi
Mori, Seiichi
Sone, Takaaki
Manabe, Osamu
Water-soluble calix<6>arenes bearing both acidic protons and sulfonate groups were synthesized.They catalyzed a hydration reaction of 1-benzyl-1,4-dihydronicotinamide (BNAH) according to Michaelis-Menten kineticts and the rate constants were greater by 426-1220 fold than those for noncyclic analogues.Fluorescence data supported the complexation of BNAH with these water-soluble calixarenes.These findings indicate that calixarenes serve as a new starting material to design functionalized host molecules.
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