Tetrahedron Letters p. 3129 - 3132 (1999)
Update date:2022-08-16
Topics:
Jung, Michael E.
Marquez, Rodolfo
It has been shown that allylic carbocations are formed in preference to tertiary or secondary carbocations in the rearrangement of substituted epoxides. However protection of the alkene as a bromo ether allows for the desired rearrangement and production of intermediates for the synthesis of the cytotoxic tedanolides.
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