Tetrahedron p. 6797 - 6812 (1999)
Update date:2022-08-04
Topics:
Breczinski, Patrick M.
Stumpf, Andreas
Hope
Krafft, Marie E.
Casalnuovo, Joseph A.
Schore, Neil E.
The major product in the intramolecular Pauson-Khand reaction of 3,4- disubstituted 1,6-heptenynes to form bicyclo[3.3.0]octenones is highly dependent on the relative configurations of the two stereocenters of the substrate. For example, cycloaddition of
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Doi:10.1248/cpb.11.823
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