Synthesis p. 777 - 779 (1993)
Update date:2022-08-16
Topics:
Crispino
Sharpless
The asymmetric dihydroxylation of methyl farnesoate resulted in regioselective dihydroxylation of the 10,11 olefin to give the (10S) and (10R)-(2E,6E)-10,11-dihydroxy-3,7,11-trimethyl-2,6-dodecadienoates in high ee. These diols were converted to juvenile hormone III and its enantiomer.
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Doi:10.1021/bc100382c
(2011)Doi:10.1002/cphc.202000071
(2020)Doi:10.1016/S0960-894X(00)00619-3
(2001)Doi:10.1038/168518b0
(1951)Doi:10.1039/c4ra03362k
(2014)Doi:10.1021/ja01867a068
(1940)
