SYNTHESIS OF 1,4-EPIMINE COMPOUNDS. IODOSOBENZENE DIACETATE, AN EFFICIENT REAGENT FOR NEUTRAL NITROGEN RADICAL GENERATION

Article abstract of DOI:10.1016/S0040-4039(00)94862-7

Photolysis of several nitroamines, cianamines, and phosphoroamidates in the presence of iodosobenzene diacetate (IBDA) and iodine leads to neutral aminyl radicals which undergo intramolecular hydrogen abstraction to produce epimine compounds with yields t