Tetrahedron Letters p. 1501 - 1504 (1984)
Update date:2022-08-28
Topics:
Fujimoto, Yoshinori
Kimura, Miki
Takasu, Akihiro
Khalifa, Fathy A. M.
Morisaki, Masuo
Ikekawa, Nobuo
Deuterated stigmasterols (10, 11 and 12) were chemically synthesized and fed to silkworm larvae.GC-MS analysis of the metabolites, cholesterol (4) and desmosterol (6), indicates the migration of 25-hydrogen to C-24position during stigmasterol dealkylation. 22,24(28)-Dienes (8a and 8b) were shown to be converted to 22,24-diene (5), desmosterol and cholesterol.
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