Journal of the Chemical Society. Chemical communications p. 1586 - 1588 (1988)
Update date:2022-08-22
Topics:
Duddeck, Helmut
Kennedy, Michael
McKervey, M. Anthony
Twohig, Fiona M.
Cyclisation of 2-diazoacetylbiphenyl with rhodium(II) acetate or mandelate yields the unstable benzazulen-10(9aH)-one from which benzazulene can be obtained by lithium aluminium hydride reduction; similar reactions with the related diazoketones (2)-(5) yield stable benzobicyclotrienones in high yield.
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