Tetrahedron Letters p. 1585 - 1588 (1987)
Update date:2022-08-11
Topics:
Bishop, Roger
Burgess, Graham
Adamantyl- or homoadamantyl-derived N-bridgehead amides are converted in high yields into hydrocarbon derivatives on prolonged reflux in ethanol and 50percent sulphuric acid (1:1 by volume).This process probably involves AAL1 hydrolysis to the tertiary carbonium ion, followed by hydride abstraction from the ethanol solvent.
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