Diverting thiamin from catalysis to destruction. Mechanism of fragmentation of N(1')-methyl-2-(1-hydroxybenzyl)thiamin

DOI: 10.1021/ja00151a001

Source and publish data:

Journal of the American Chemical Society p. 11383 - 11389 (1995)

Update date:2022-08-10

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Authors:

Kluger Kluger

Lam Lam

Pezacki Pezacki

Yang Yang

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Article abstract of DOI:10.1021/ja00151a001

Thiamin (1) promotes reactions involving acyl carbanion equivalents derived from benzaldehyde through a covalent intermediate, 2-(1-hydroxybenzyl)thiamin (HBzT, 2). HBzT reverts to benzaldehyde and thiamin in alkaline solution. However, in neutral solutio

Full text of DOI:10.1021/ja00151a001

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