Diverting thiamin from catalysis to destruction. Mechanism of fragmentation of N(1')-methyl-2-(1-hydroxybenzyl)thiamin

DOI: 10.1021/ja00151a001

Source and publish data:

Journal of the American Chemical Society p. 11383 - 11389 (1995)

Update date:2022-08-10

Topics:

Authors:

Kluger Kluger

Lam Lam

Pezacki Pezacki

Yang Yang

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00151a001

Thiamin (1) promotes reactions involving acyl carbanion equivalents derived from benzaldehyde through a covalent intermediate, 2-(1-hydroxybenzyl)thiamin (HBzT, 2). HBzT reverts to benzaldehyde and thiamin in alkaline solution. However, in neutral solutio

Full text of DOI:10.1021/ja00151a001

Products guided by the article

Product name:Methanone, [5-(2-hydroxyethyl)-4-methyl-2-thiazolyl]phenyl-

Cas No:28168-40-3

R&D Labs maybe for 28168-40-3

Shandong Zhongcheng Barium Salt Co., Ltd

Contact:+86-15725732638

Address:No.29 baoxi road, hi-tech zone, zibo, shandong
Suzhou Howsine Biological Technology Co.,Ltd(expird)

website:http://www.howsine.com

Contact:86-512-67262751

Address:No 3,Weihua Road ,Suzhou Industrial Park ,Jiangsu ,China.
NEW FORTUNE INDUSTRIAL CO.,LTD.

website:http://newfortune.lookchem.com/

Contact:+86-25-8645-9456

Address:C4-105 GREEN ISLAND FLOWER TOWN
Hangzhou Fandachem Co.,Ltd

Contact:+86-158-5814-5714

Address:No.9 YanAn Road,Hangzhou,Zhejiang,China
Improve Medical Technology(Nanxiong) Co., Ltd

Contact:86-751-3836997

Address:No.33, Pingan First Road, Fine Chemical Industry Base, Nanxiong City, Shaoguan, Guangdong, China

Relevant to this article

Asymmetric α-alkylation of α-amino esters using pyridoxal derivatives having a chiral ansa-structure and a chiral ionophore function: A novel example of double asymmetric induction

Doi:10.1016/S0040-4020(00)00392-6
(2000)
Sol-gel hydrothermal synthesis of microstructured CaO-based adsorbents for CO₂ capture

Doi:10.1039/c4ra14355h
(2015)
Facile routes to alkoxymaleimides/maleic anhydrides

Doi:10.1055/s-2003-37351
(2003)
Tetranuclear vanadium complex, (VO)₄(hpic)₄: A recyclable catalyst for oxidation of benzyl alcohols with molecular oxygen

Doi:10.1039/b913823d
(2009)
Investigation of mononuclear, dinuclear, and trinuclear transition metal (II) complexes derived from an asymmetric Salamo-based ligand possessing three different coordination modes

Doi:10.1002/aoc.6040
(2021)
Studies on the constituents of Trichosanthes species. I. On the neutral ether extracts of the dried roots of Trichosanthes japonica Regel, Trichosanthes kirilowii Maxim. and Trichosanthes cucumeroides Maxim.

Doi:10.1248/cpb.30.2570
(1982)

Article Doi