SELECTIVE SYNTHESIS OF 3,5-DISUBSTITUTED ISOAZOLES FROM β-SUBSTITUTED ENONES AND HYDROXYLAMINE HYDROCHLORIDE IN THE PRESENCE OF VARIOUS BASES

DOI: 10.1246/cl.1982.1455

Source and publish data:

Chemistry Letters p. 1455 - 1458 (1982)

Update date:2022-08-30

Topics:

Authors:

Kashima, Choji

Yoshiwara, Nobutoshi

Shirai, Shun-ichi

Omote, Yoshimori

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Article abstract of DOI:10.1246/cl.1982.1455

The synthesis of two isomeric isoxazoles could be selectively controlled in the reaction of β-substituted enones with 3 species of hydroxylamine; hydroxyammonium cation (1), free hydroxylamine (2) and aminoHydroxy anion (3).

Full text of DOI:10.1246/cl.1982.1455

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