Journal of the Chemical Society. Perkin transactions II p. 1869 - 1873 (1984)
Update date:2022-08-17
Topics:
Morgan, Morag E.
Osborne, David A.
Waddington, David J.
The photo-oxidation of mixtures of trans-2,2'-azoisobutane and some aliphatic alkenes has been studied between 313 and 393 K.Rate constants for the reaction between t-butylperoxyl radicals with ethene, 2-methylpropene, 2-methylbut-1-ene, 2-methylbut-2-ene, and 2,3-dimethylbut-2-ene have been determined at 393 K.Arrhenius parameters for the reaction (22) have been determined for 2-methylbut-2-ene and 2,3-dimethylbut-2-ene.They are log (A22/dm3mol-1s-1) of 8.16+/-0.38 and 8.58+/-0.61, and E22/kJ mol-1 of 56.6+/-2.4 and 48.7+/-4.1, respectively.The data obtained in this work are compared with that obtained for the series hydroperoxyl, and isopropylperoxyl radicals, and with rate data obtained for the addition reaction between alkenes and peracetyl radicals.
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