Tetrahedron Letters p. 2543 - 2546 (1988)
Update date:2022-08-10
Topics:
Turro, N. J.
Zhang, Z.
Trahanovsky, W. S.
Chou, C.-H.
Photolysis of benzocyclobutene (1) in pentane solution at 254 nm yields 1,2-dihydropentalene (2) and 1,5-dihydropentalene (3) as the major isomeric products; formation of 2 and 3 is consistent with a "prebenzvalene"-carbene rearrangement mechanism.
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