Reduction of polyhalofluoroalkanes with formate to hydrogen-bearing alternatives initiated by carbon dioxide anionic radical

DOI: 10.1016/S0022-1139(00)81259-2

Source and publish data:

Journal of Fluorine Chemistry p. 105 - 108 (1991)

Update date:2022-08-11

Topics:

Authors:

Hu, Chang-Ming

Tu, Ming-Hu

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Article abstract of DOI:10.1016/S0022-1139(00)81259-2

Reduction of polyhalofluoroalkanes with formate in the presence of a catalytic amount of persulfate is described.Such a reagent posseses good selectivity in the reduction of carbon-chlorine bonds.A chain mechanism including carbon dioxide anionic radicals and polyhalofluoroalkyl radicals is proposed.

Full text of DOI:10.1016/S0022-1139(00)81259-2

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