Organic and Biomolecular Chemistry p. 8724 - 8734 (2020)
Update date:2022-08-17
Topics:
Mora Flores, Erwin W.
Postigo, Al
Uhrig, María Laura
A benign, efficient, regio- and stereoselective protocol for the syntheses of α-1-fluoroalkyl-C-glycosyl compounds bearing CF3, C4F9, and C6F13 substituents on the anomeric carbon has been developed by a new methodology starting from 2-acetoxyglycals for the first time. Remarkably, the reactions proceeded in only one step, through the visible light-photocatalyzed reductive fluoroalkylation of 2-acetoxyglycals by means of an Ir photocatalyst and employed commercially available fluoroalkyl iodides n-CnF2n+1-I (n = 1, 4, 6) as a source of fluoroalkyl radicals.
View Moreshijiazhuang alkay chemicals co..ltd
Contact:86-311-67692035
Address:2601,juntang building,qiaodong district,shijiazhuang
Hebei Lead Bio-Chemicals Co., Ltd.
website:http://www.ldbiochem.com
Contact:+86-311-87826503
Address:481, Heping West Road, Shijiazhuang,China
Contact:410-273-7300; 800-221-3953
Address:4609 Richlynn Dr., PO Box 369, Belcamp, MD, 21017-0369, USA
Shanghai Sunwise Chemical Co., Ltd
website:http://www.sunwisechem.com
Contact:86-021-33883180
Address:Room 10E, Building G, Westlink Center, No. 2337 Gudai Road, Minhang District, Shanghai, China PC: 201100
qingdao goldenchem imp and exp co.,ltd.
Contact:532-55579246
Address:no.62 ,haier road laoshan distirct
Doi:10.1080/00304948.2019.1600132
(2019)Doi:10.1039/c5ra09055e
(2015)Doi:10.1007/s11746-000-0040-6
(2000)Doi:10.1139/v69-275
(1969)Doi:10.1007/BF01488193
(1939)Doi:10.1002/hlca.19810640323
(1981)