Chemistry of Oxaziridines. 10. Selective Catalytic Oxidation of Sulfides to Sulfoxides Using N-Sulfonyloxaziridines

DOI: 10.1021/jo00256a018

Source and publish data:

Journal of Organic Chemistry p. 5004 - 5007 (1988)

Update date:2022-08-11

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Authors:

Davis, Franklin A.

Lal, Sankar G.

Durst, H. Dupont

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Article abstract of DOI:10.1021/jo00256a018

The chemoselective catalytic oxidation of aliphatic and aromatic sulfides to sulfoxides (90-95percent) using a buffered potassium peroxymonosulfate (Oxone) generated N-sulfonyloxaziridine is described.This oxidizing system is rapid and relatively intensitive to the reaction parameters and the structure of the sulfide.

Full text of DOI:10.1021/jo00256a018

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