Rearrangement and photolysis of aziridines in the aspidosperma series

DOI: 10.1016/S0040-4039(98)01626-8

Source and publish data:

Tetrahedron Letters p. 7503 - 7506 (1998)

Update date:2022-08-11

Topics:

Authors:

Hoffmann, Norbert

Hugel, Georgette

Nuzillard, Jean-Marc

Royer, Daniel

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Article abstract of DOI:10.1016/S0040-4039(98)01626-8

Rearrangement of aziridine 1 by MgBr₂ gave 2-H-dihydro-17- dehydrovincadifformine 6. Photolysis transformed aziridines 1 and 11 into the new compounds 1,2-seco-1,21-cyclovincadifformine 10 and 1,2-seco-1,21- cyclotabersonine 12.

Full text of DOI:10.1016/S0040-4039(98)01626-8

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Product name:Aspidospermidine-3-carboxylic acid, 2,3-didehydro-, methyl ester, (5α,12β,19α)-

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