Preparation of Useful Chiral Lactone Synthons via Stereospecific Enzyme-catalysed Oxidations of meso-Diols

DOI: 10.1039/c39800000515

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Journal of the Chemical Society. Chemical communications p. 515 - 516 (1980)

Update date:2022-08-30

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Authors:

Jakovac, Ignac J.

Ng, George

Lok, Kar P.

Jones, J. Bryan

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Article abstract of DOI:10.1039/c39800000515

Horse liver alcohol dehydrogenase-catalysed oxidations of symmetrical acyclic and cyclic meso-diol substrates give chiral γ- and δ-lactones in high yields and of 100percent enantiomeric excess and provide access to a broad range of useful synthons of value in asymmetric syntheses of natural products.

Full text of DOI:10.1039/c39800000515

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